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Beilstein J. Org. Chem. 2013, 9, 1745–1750, doi:10.3762/bjoc.9.201
Graphical Abstract
Scheme 1: Formation of azirines 2 from vinyl azides 1, photoinduced ring-opening to the nitrile ylides 3, and...
Scheme 2: Solid-phase assisted synthesis of vinyl azides 1 from alkenes 6 under flow conditions [9].
Scheme 3: Schematic presentation of the flow set-up for the synthesis of 2H-azirines 2 under inductive heatin...
Scheme 4: Photoinduced cycloadditions of vinyl azides 1a–f and electron-deficient alkenes 4a–d. All experimen...
Scheme 5: Photoinduced cycloaddtion of vinyl azide 1c and diisopropyl azodicarboxylate (4e). The experiment w...
Scheme 6: Photoinduced cycloaddtion of vinyl azide 1b and alkyne 4f. The experiment was conducted at room tem...
Scheme 7: Formation of 2,5-dihydrooxazole 9 starting from vinyl azide 1g under flow conditions (c = 0.01 M, f...
Beilstein J. Org. Chem. 2011, 7, 1441–1448, doi:10.3762/bjoc.7.168
Scheme 1: Hassner's synthesis of vinyl azides and a stable, nonexplosive analogue 5 of iodine azide (1).
Scheme 2: Preparation of polymer-bound bisazido iodate(I) 5 and polymer-bound 1,8-diaza-[5.4.0]bicyclo-7-unde...
Scheme 3: Two-step protocol for the preparation of vinyl azides 4a–e and 4g–i under flow conditions.
Scheme 4: Regeneration of functionalized polymers 5 and 8.
Scheme 5: Preparation of triazoles 12a–l by using inductively heated copper turnings as a packed-bed material...